Stern理论扩散双电层构造[45]

下载：全尺寸图片幻灯片

Stern理论扩散双电层构造^[45]

表面活性位点反应	双层模型参数(lgK)	非静电模型参数(lgK)
$ \equiv X{\text{Na}} \rightleftharpoons \equiv {X^ - } + {\text{N}}{{\text{a}}^ + } $	-1.58	-1.58
$ \equiv X{\text{Na}} + {{\text{H}}^ + }f \equiv XH + {\text{N}}{{\text{a}}^ + } $	1.50	2.10
$ \equiv {\text{AlOH}} + {{\text{H}}^ + }f \equiv {\text{AlOH}}_{\text{2}}^{\text{ + }} $	6.15	5.83
$ \equiv {\text{AlOH}} + {\text{O}}{{\text{H}}^ - }f \equiv {\text{AlO + H}}_{\text{2}}^{}{\text{O}} $	-9.27	-7.02
$ \equiv {\text{SiOH}} + {\text{O}}{{\text{H}}^ - }f \equiv {\text{Si}}{{\text{O}}^ - }{\text{ + H}}_{\text{2}}^{}{\text{O}} $	-9.06	-8.75