MgO间接碳化固化黏土的物理力学性能研究

    Physico-mechanical properties of clay stabilized by magnesium oxide-mediated indirect carbonation

    • 摘要: 传统的活性氧化镁(MgO)碳化技术是一种新兴的土体固化方法。然而,由于该技术需要在特定浓度和压力下通入CO2,在实际工程应用中难以控制,容易导致固化不均匀,特别是对于黏性土。为了解决这一问题,研究采用碳酸氢钠(NaHCO3)作为CO2的载体,通过间接碳化的方法对MgO固化黏土进行处理。采用无侧限抗压强度(UCS)、含水率、X射线衍射(XRD)等实验方法,探讨了MgO和NaHCO3的比例、养护龄期、温度及酸性条件对间接碳化加固黏土的力学性能和膨胀性的影响。结果表明:无侧限抗压强度随着NaHCO3掺量的增加先增大后减小,在MgO∶NaHCO3=2∶1时达到最大;随着龄期的延长和温度的升高,强度总体上不断增加。在强度和抗膨胀性能方面,MgO∶NaHCO3=2∶1的配比优于直接碳化固化土。XRD结果显示,碳化土的无侧限抗压强度主要由球碳镁石或三水菱镁石、水碳镁石晶体提供。

       

      Abstract: The traditional reactive magnesium oxide (MgO) carbonation technology is an emerging soil stabilization method. However, since this technique requires CO₂ to be introduced at specific concentrations and pressures, it is challenging to control in practical engineering applications, often leading to uneven solidification, especially for clayey soils. To address this issue, the sodium bicarbonate (NaHCO3) is used as a CO₂ carrier to treat the MgO-stabilized clay by an indirect carbonation method. The UCS, moisture content and XRD tests are conducted to investigate the effects of MgO and NaHCO3 ratios, curing age, temperature and acidic conditions on the mechanical properties and expansibility of clay reinforced by the indirect carbonation. The results indicate that the UCS initially increases and then decreases with the addition of NaHCO3, reaching its peak at an MgO: NaHCO3 ratio of 2:1. With extended curing time and elevated temperatures, the strength generally increases. In terms of strength and anti-expansion performance, the MgO: NaHCO3 ratio of 2:1 outperforms direct carbonation-stabilized soil. The XRD results show that the UCS of carbonated soil is mainly provided by hydromagnesite, or dypingite.

       

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