含盐膨润土导热性能的温度效应

    Temperature effects of thermal conductivity of salted bentonite

    • 摘要: 含盐膨润土导热性能的温度效应对于核废料深地处置库设计至关重要。通过盐溶液对MX80膨润土粉进行盐化调湿处理,并基于热探针法测试了不同温度下含盐膨润土导热性能,并分析了不同温度下膨润土相对湿度随盐分特征的响应规律。结果表明:含盐膨润土导热性能的温度效应与无盐膨润土相似,导热系数都随温度升高而增大,但温度对含盐膨润土导热性能的强化程度要弱于无盐膨润土;相同盐分类型下随浓度升高,含盐膨润土导热性能的温度效应快速弱化;相同盐分浓度下,不同盐分类型含盐膨润土导热性能的温度效应不同,呈现CaCl2 < NaCl < KCl。含盐膨润土导热性能温度效应的演化机理归因于盐分降低了土内相对湿度,部分抵消了温度通过水汽潜热传输对导热性能的贡献。

       

      Abstract: The temperature effects of thermal conductivity of salted bentonite are crucial for the design of deep-earth repositories for nuclear waste. MX80 bentonite powder is salinized and humidified by salt solution, the thermal conductivity of salted bentonite is measured at different temperatures based on the thermal probe method, and its relative humidity is also analyzed later. The results show that the temperature effects of thermal conductivity of salted bentonite are similar to those of pure bentonite, and the thermal conductivity increases with temperature, but the increase in the thermal conductivity of salted bentonite is weaker than that of pure bentonite. With the increase in the salt concentration with the same type, the temperature effects of thermal conductivity of salted bentonite are gradually weakened. Under the same salt concentration with different salt types, the temperature effects of thermal conductivity of salted bentonite are different from each other, showing CaCl2 < NaCl < KCl. The evolution mechanism of the temperature effects is attributed to that salt reduces the relative humidity in pore gas, partially offsetting the contribution of temperature to thermal conductivity through latent heat transfer.

       

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