结构性深海固碳黏土的离散元模拟方法研究

    Discrete element method for structural carbon dioxide hydrate-bearing clay

    • 摘要: 二氧化碳(CO2)置换法在深海能源黏土中规模开采天然气对减少碳排放和维持地层稳定具有重要意义。置换开采过程中含有CO2水合物的黏土沉积物称为深海固碳黏土。通过分析现有室内试验数据绘制出甲烷CH4-CO2双组分水合物相平衡线,建立环境参数L与CO2水合物强度、弹性模量的关系,并将其引入本团队开发的胶结型深海能源黏土三维离散元接触模型,最终建立能够考虑CO2摩尔分数影响的结构性深海固碳黏土三维胶结接触模型;基于该模型开展等向压缩试验和常规三轴压缩试验离散元模拟,并与室内试验进行对比分析。结果表明:基于所建立的结构性深海固碳黏土三维胶结接触模型的离散单元法能够表征不同环境条件下深海固碳黏土力学特性的变化规律,为深入开展深海水合物开发利用提供了技术参考。

       

      Abstract: The large-scale exploitation of methane hydrate-bearing clay through carbon dioxide displacement holds significant importance in reducing carbon emissions and maintaining strata stability. The clay sediment containing CO2 hydrates during the replacement process is called carbon dioxide hydrate-bearing clay. By analyzing the experimental data available in literatures, the phase equilibrium curve of methane-carbon dioxide hydrate is obtained. The relationships among the condition parameter L, strength and elastic modulus of carbon dioxide hydrates are established. These relationships can be incorporated into the microscopic contact model for grain-cementing type methane hydrate-bearing clay in the discrete element method (DEM) to finally build a three-dimensional contact model of grain-cementing type for the structured carbon-dioxide hydrate-bearing clay. The model can consider the effects of different carbon dioxide mole fractions. Based on the built contact model, a series of isotropic compression tests and conventional triaxial compression tests are conducted through the DEM simulation, and the simulated results are compared with the present laboratory experimental ones. The results show that the proposed contact model in this study can characterize the change laws of mechanical properties of the structured carbon dioxide hydrate-bearing clay, which can provide technical reference for the exploitation and utilization of methane hydrate in the future.

       

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