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付贵永, 肖杨, 史金权, 周航, 刘汉龙. 干湿循环下EICP联合黄原胶加固钙质粉土劣化特性试验研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20230748
引用本文: 付贵永, 肖杨, 史金权, 周航, 刘汉龙. 干湿循环下EICP联合黄原胶加固钙质粉土劣化特性试验研究[J]. 岩土工程学报. DOI: 10.11779/CJGE20230748
Degradation of EICP and Biopolymer Treated Calcareous Silt Under Dry-wet Cycles[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20230748
Citation: Degradation of EICP and Biopolymer Treated Calcareous Silt Under Dry-wet Cycles[J]. Chinese Journal of Geotechnical Engineering. DOI: 10.11779/CJGE20230748

干湿循环下EICP联合黄原胶加固钙质粉土劣化特性试验研究

Degradation of EICP and Biopolymer Treated Calcareous Silt Under Dry-wet Cycles

  • 摘要: 生物聚合物(BP)是近年来一种新兴的环境友好型土体加固生物材料,然而因其具有水溶性,BP固化土在循环浸水工况下强度逐渐劣化。因此,提高BP加固土的耐侵水性十分重要。本文通过植物脲酶诱导碳酸钙沉(EICP)联合黄原胶(XG)对南海钙质粉土进行加固,对不同干湿循环次数下的固化粉土进行了无侧限压缩试验和剪切波速测试试验,并开展了EICP和XG-EICP溶液沉淀试验,利用扫描电子显微镜(SEM)和X射线能谱分析(EDS)对联合固化土的微观孔隙结构和沉淀结构进行了分析。研究结果表明:随着黄原胶含量和EICP反应液浓度的增加,黄原胶(XG)固化土和联合(XG-EICP)固化土的无侧限抗压强度提升显著;随着干湿循环次数的增加,黄原胶固化土的强度降幅大于联合固化土,联合固化土具有更优的抗干湿循环特性。黄原胶在粉土颗粒孔隙中以纤维网状结构存在,EICP溶液为黄原胶交联改性提供了充足的Ca2+,且EICP矿化结晶还为黄原胶提供了更多的连接位点,使得联合固化土力学性质更稳定。EICP和XG-EICP溶液试验结果表明:XG在EICP溶液中可以生成不溶于水的凝胶状沉淀,且粘连在XG-EICP沉淀上的碳酸钙颗粒较其纯EICP生成得碳酸钙颗粒体积更大。本试验验证了植物脲酶诱导碳酸钙沉淀提高生物聚合物固化土抗干湿循环侵蚀的可行性,有望为海洋土加固提供新的思路与方法。

     

    Abstract: Biopolymer (BP) is an emerging environment-friendly biomaterial for soil reinforcement in recent years. However, due to its water solubility, the strength of BP-stabilized soil gradually deteriorates under cyclic dry-wet conditions. Therefore, it is very important to improve the water resistance of BP-strengthened soil. In this paper, the calcareous silt in the South China Sea was reinforced by plant urease-induced calcium carbonate precipitation (EICP) combined with xanthan gum (XG). The unconfined compression test and shear wave velocity test were carried out on the solidified silt under different drying and wetting cycles. EICP and XG-EICP solution precipitation tests were carried out as well, and the microscopic pore structure of the combined solidified soil and pure precipitate without soils were analyzed by scanning electron microscopy (SEM) and X-ray energy spectrum analysis (EDS). The test results show that: with the increase of xanthan gum content and plant urease concentration, the unconfined compressive strength of xanthan gum (XG) stabilized soil and joint (XG-EICP) stabilized soil increased significantly; With the increase of dry-wet cycles, the strength decrease of xanthan gum-stabilized soil is greater than that of joint-stabilized soil, and joint-stabilized soil has better resistance to dry-wet cycles. Xanthan gum exists in a fibrous network structure in the pores of silt particles, and the EICP solution provides sufficient Ca2+ for the cross-linking modification of xanthan gum, and the mineralized crystallization of EICP also provides more connection sites for xanthan gum, making the mechanical properties of the combined solidified soil more stable. The test results of EICP and XG-EICP solutions show that: XG can form a water-insoluble gel-like precipitate in EICP solution, and the calcium carbonate particles attached to the XG-EICP precipitate are larger than those produced by pure EICP. This experiment verified the feasibility of EICP to improve the erosion resistance of biopolymer-solidified soils against dry-wet cycles, and is expected to provide new ideas and methods for marine soil reinforcement.

     

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