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SJP注浆浆液水化进程与流变特性研究

裴向军, 张佳兴, 王文臣, 杨福田

裴向军, 张佳兴, 王文臣, 杨福田. SJP注浆浆液水化进程与流变特性研究[J]. 岩土工程学报, 2017, 39(2): 201-209. DOI: 10.11779/CJGE201702002
引用本文: 裴向军, 张佳兴, 王文臣, 杨福田. SJP注浆浆液水化进程与流变特性研究[J]. 岩土工程学报, 2017, 39(2): 201-209. DOI: 10.11779/CJGE201702002
PEI Xiang-jun, ZHANG Jia-xing, WANG Wen-chen, YANG Fu-tian. Hydration process and rheological properties of SJP cement paste[J]. Chinese Journal of Geotechnical Engineering, 2017, 39(2): 201-209. DOI: 10.11779/CJGE201702002
Citation: PEI Xiang-jun, ZHANG Jia-xing, WANG Wen-chen, YANG Fu-tian. Hydration process and rheological properties of SJP cement paste[J]. Chinese Journal of Geotechnical Engineering, 2017, 39(2): 201-209. DOI: 10.11779/CJGE201702002

SJP注浆浆液水化进程与流变特性研究  English Version

基金项目: 国家自然科学基金项目(40402025); 成都理工大学地质灾害防治与地质环境保护国家重点实验室团队重点项目(SKLGP2014Z001)
详细信息
    作者简介:

    裴向军(1970- ),男,教授,博士生导师,主要从事地质灾害、工程边坡稳定性评价与工程治理方面的教学与科研工作。E-mail:peixj0119@tom.com。

    通讯作者:

    张佳兴,E-mail:zjx1992@outlook.com

Hydration process and rheological properties of SJP cement paste

  • 摘要: 针对陡倾宽缝、松散架空等复杂地层灌浆,普通水泥浆存在“灌不住”、“顺缝跑”等问题,研制开发的SJP水泥基灌浆材料具有初始流动度大、可灌性好,接近可泵期时表现为黏度突增、流动度突降的流变特性。SJP浆材是水泥基浆材掺加改性纤维、硅钙早强剂与稳定剂配制而成,助剂加量为2%~2.5%。掺入水泥浆中的助剂首先在水泥颗粒表面形成溶剂膜,起到调节水泥水化离子与助剂硅钙阳离子浓度变化的作用,实现水化加速期控制成核的速度,最后掺入的稳定剂可以调整水泥水化衰减期的成核和扩散,调节水泥浆的流动时间。SJP浆材由于水化速度快,流动时间可控,水化产物凝结胶连紧密,结石体后期强度较普通水泥浆平均提高15%~25%,解决了水泥基速凝浆材早期强度高后期强度低的问题,得到了较大范围的推广应用。
    Abstract: Qwing to that the common cement paste used in the complex soil strata with wide steep seams and loose space cannot fill firmly and run along the gaps, a new type of SJP cement paste is developed, which has great initial fluidity and good groutability. Its apparent viscosity can suddenly increase and its fluidity of the rheological properties can suddenly drop during pumping. The SJP cement paste is made from modified fiber, CaSi early strength agent and cement, with the amount of additive agent of 2%~2.5%. The additives first form the solvent membrane in the surface of cement particles, which can adjust the ion concentration of cement hydration and CaSi cationic. The role of controlling the speed of nucleation at the acceleration stage is achieved. The retardation stage of SJP paste is controlled by the nucleation and diffusion process, and the stable stage is mainly controlled by the effect of diffusion. Because of the high speed of hydration, controllable flowing time and are closely cemented hydration products, the later strength of solidified paste is improved by 15%~25% higher than that of the common cement paste. The SJP paste can solve the problem of higher early strength and lower later strength. So it has got a larger range of popularization and application.
  • [1] 闫 勇, 郑秀华. 水泥-水玻璃浆液性能试验研究[J]. 水文地质工程地质, 2004, 31(1): 71-72, 81. (YAN Yong, ZHENG Xiu-hua. Experimental research on performance of grout of cement and sodium silicate[J]. Hydrogeology and Engineering Geology, 2004, 31(1): 71-72, 81. (in Chinese))
    [2] 吕智英, 张 健, 王秀琴. 氨基磺酸盐高效减水剂与聚醚多糖复合对水泥浆性能的影响[J]. 南阳师范学院学报, 2007(9): 45-49. (LU Zhi-ying, ZHANG Jian, WANG Xiu-qin. Influence of the compound of am inosulfonic acid-based superplasticzer and water-retentive and thickening admixture to cement paste capability[J]. Journal of Nanyang Normal University, 2007(9): 45-49. (in Chinese))
    [3] 张玉佩, 申向东. 聚丙烯酰胺对水泥土强度影响的试验研究[J]. 硅酸盐通报, 2012, 31(6): 1636-1640. (ZHANG Yu-pei, SHEN Xiang-dong. Experimental study the impacts of PAM on cement soil strength[J]. Bulletin of the Chinese Ceramic Society, 2012, 31(6): 1636-1640. (in Chinese))
    [4] 裴向军, 黄润秋, 李正兵, 等. 锦屏一级水电站左岸卸荷拉裂松弛岩体灌浆加固研究[J]. 岩石力学与工程学报, 2011, 30(2): 285-288. (PEI Xiang-jun, HUANG Run-qiu, LI Zheng-bing, et al. Research on grouting reinforcement of unloading fractured loose rock mass in left bank of Jinping Ⅰhydropower station[J]. Chinese Journal of Rock Mechanics and Engineering, 2011, 30(2): 285-288. (in Chinese))
    [5] DABIC P, KRSTULOVIC R, RUSIC D. A new approach in mathematical modeling of cement hydration development[J]. Cement and Concrete Research, 2000, 30(7): 10177-1021
    [6] 彭小芹, 兰 聪, 王淑萍, 等. 水化硅酸钙粉体对水泥水化反应过程及机理的影响[J]. 建筑材料学报, 2015, 18(2): 195-201. (PENG Xiao-qin, LAN Cong, WANG Shu-ping, et al. Effects of the C-S-H powder on the hydration process and mechanism of cement[J]. Journal of Building Materials, 2015, 18(2): 195-201. (in Chinese))
    [7] MOSTAFA N Y, BROWN P W. Heat of hydration of highreactive pozzolans in blended cement: Isothermal conduction calorimetry[J]. Thermochimica Acta, 2005, 435(2): 162-167.
    [8] 施惠生, 黄小亚. 硅酸盐水泥水化热的研究及其进展[J]. 水泥, 2009(12): 4-10. (SHI Hui-sheng, HUANG Xiao-ya. Research and progress of Portland cement hydration heat[J]. Cement, 2009(12): 4-10. (in Chinese))
    [9] TAYLOR H F W. Cement chemistry[M]. London: Academic Press, 1990: 325-337.
    [10] KONDO R, UEDA S. Kinetics of hydration of cement[C]// 5th International Conference on the Chemistry of Cement Sess II-4. Tokyo, 1968: 203-208.
    [11] KNUDSEN T. Onparticle size distribution in cementhydration[C]// Proceedings of 7th International Congress on the Chemistry of Cement. Vol I. Paris, 1980, 170.
    [12] 傅献彩, 沈文霞, 姚天扬. 物理化学[M]. 4版. 北京: 高等教育出版社, 1990: 700-770. (FU Xian-cai, SHEN Wen-xia, YAO Tian-yang. Physical chemistry[M]. 4th ed. Beijing: Higher Education Press, 1990: 700-770. (in Chinese))
    [13] 刘伯谦, 吕 太. 逾渗理论应用导论[M]. 北京: 科学出版社, 1988. (LIU Bo-qian, LÜ Tai. Introduction to the application of percolation theory[M]. Beijing: Science Press, 1988. (in Chinese))
    [14] 董秀荣. 化学外加剂对高性能水泥水化及初始结构形成调控机理的研究[D]. 武汉: 武汉理工大学, 2005. (DONG Xiu-rong. Research on control mechanism of chemical admixtures on cement hydration and initial structure formation[D]. Wuhan: Wuhan University of Technology, 2005. (in Chinese))
    [15] 阮文军, 王文臣, 胡安兵. 新型水泥复合浆液的研制及其应用[J]. 岩土工程学报, 2001, 23(2): 212-216. (RUAN Wen-jun, WANG Wen-chen, HU An-bing. Development and application of new kind of cement composite grout[J]. Chinese Journal of Geotechnical Engineering, 2001, 23(2): 212-216. (in Chinese))
    [16] 邝建政, 昝月稳, 王 杰, 等. 岩土注浆理论与工程实例[M]. 北京: 科学出版社, 2001: 49-52. (KUANG Jian-zheng, ZAN Yue-wen, WANG Jie, et al. Theory and engineering examples of rock and soil grouting[M]. Beijing: Science Press, 2001: 49-52. (in Chinese))
    [17] 阮文军. 注浆扩散与浆液若干基本性能研究[J]. 岩土工程学报, 2005, 27(1): 69-73. (RUAN Wen-jun. Research on diffusion of grouting and basic properties of grouts[J]. Chinese Journal of Geotechnical Engineering, 2005, 27(1): 69-73. (in Chinese))
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出版历程
  • 收稿日期:  2015-12-01
  • 发布日期:  2017-03-24

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